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SMT-Feb2015

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36 SMT Magazine • February 2015 in some local regions, the further energy gain can be achieved via the diameter increase (i.e., whiskers get thicker intermittently with the pe- riods of faster length increase). A snapshot of many such whisker lengths and diameters will therefore show broad statistical distributions that are mutually uncorrelated. Figure 7 illustrates the process of whisker growth in a 2D fashion where the color coding is such that upward and downward local elec- tric field directions are shown in respectively red and blue. The sign fluctuations of the field at large distances shown in Figure 5 do not eliminate the polarization energy gain. Indeed, consider a long metal whisker as a succession of many small metal rods, each occupying a small range of more or less constant field. They have local dipole moments p=aE, and partial electro- static energies pE=aE2 that are quadratic in field and do not cancel each other. Taking into ac- count the explanation in Figures 3 and 5, it is intuitively clear that the maximum polarization and electrostatic energy gain are achieved for the "color-matched" whiskers (all in blue or all in red). The corresponding pathways for whis- ker growth can be kinked in order to collect as many as possible color matched regions. This explains how whiskers can be kinked. It should be noted however that each kink entails certain deformation energy loss, so the whisker geom- etry will optimize between the gain in electro- static energy and loss in deformation energy due to kinking. (These subtle features remain unaccounted quantitatively in the current elec- trostatic whisker theory.) Furthermore, some configurations of color-matched regions pres- ent pathways parallel or partially parallel to the surface; this explains the observed longitudinal or circumferential striations shown in dash in Figure 7. 6. In the course of growing at h>>L, whis- kers encounter rare local regions of abnormally low electric fields where its further growth is blocked. The blockage is due to the fact that further growth in these low field regions can- not overweigh the energy loss due to increase in surface area: the latter increase presents a signifi- Figure 6: Sketch of the whisker growth rates vs. time. Solid lines represent the two limiting cases within the domains of their applicability (h<>l, respectively). The dashed curves are formal solutions presented by the first and the second equations in the formula displayed above. The dash-dotted line shows a hypothetical sewing. Figure 7: A sketch of whisker growth through a space of a fluctuating electric field: • rapid growth while either + or – fields dominate along the length. • For large lengths, + and – fields start balancing each other. • Whiskers stop growing at certain random lengths, which explains whisker statistics. • Can resume growth after a while. eLeCTrOSTaTIC MeCHaNISM OF NuCLeaTION aNd GrOWTH OF MeTaL WHISKerS continues Feature

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